Molecular weight of UHMW polymers with AF4-MALS

Asymmetric flow field flow fractionation (AF4) of polymers using a multi-angle light scattering (MALS) detector.

This analysis is suitable for polymers of ultra-high molecular weight (UHMW) >1E6 g/mol. This includes polymers such as polyisoprene (synthetic and natural rubber), polybutadiene, styrene-butadiene rubbers, polyisobutylene, or acrylic and methacrylic emulsion copolymers. AF4-MALS also provides superior separation of branched polymers.

The technique will measure the molecular weight distribution of polymer samples in a graphical format, the dispersity, Đ, and determine the actual molecular weight averages, Mn, Mw, and Mz.

The samples must be soluble or able to be measured from a solution at room temperature. The type of polymer and the necessary solvent will affect the cost. Please contact our experts for a quote tailored to your needs.

Suitable sample matrices
Polymers soluble in the following solvents at room temperature: THF, DMF, CHCl3, DMAc, DMSO, toluene, HFIP, or aqueous solutions. Analysis of polymers requiring other solvents may be possible upon request
Required sample quantity
100 mg
Available quality systems
Accredited testing laboratory
Device types

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