Solid recovered fuels (SRF) analysis

Smoke and toxicity testing by IMO 2010 FTP Code Part 2 is performed on surface materials to assess their suitability for marine use. The specimen is placed in a horizontal position under a cone radiator inside a smoke-density chamber. During the test, the specimen starts to emit smoke, which is collected in the closed chamber. The density of smoke is detected optically. When making toxicity measurements with FTIR, the concentrations of carbon monoxide (CO), hydrogen chloride (HCl), hydrogen bromide (HBr), hydrogen fluoride (HF), hydrogen cyanide (HCN), nitrogen oxides NO_x (NO + NO₂), and sulfur dioxide (SO₂) are measured. Classification criteria for smoke An average (D_m) of the maximum of D_s of three tests at each test condition should be within the following limits: D_m 200 for materials used as the surface of bulkheads, linings, or ceilings, D_m 400 for materials used as a primary deck covering, D_m 500 for materials used as a floor covering , D_m 400 for plastic pipes and electric cables. Classification criteria for toxicity The gas concentrations measured at each test condition should be within the following limits: CO 1450 ppm, HCl 600 ppm, HBr 600 ppm, HF 600 ppm, HCN 140 ppm , NO_x 350 ppm , SO₂ 120 ppm (200 ppm for flooring).

The burning rate of horizontally mounted materials designed to be used in vehicles and buses must be tested with the UN/ECE R118 annex 6 test before they can be approved for use. Measurlabs offers this and the other R118 tests with accreditation. In the test method, the exposed side of the test specimen is burned from underneath and the burning rate is measured and expressed in mm/min.

BET (Brunauer–Emmett–Teller) analysis to determine the specific surface area of solid materials.

The melting behavior of fusible materials used in certain motor vehicles must be determined according to Annex 7 of UN/ECE Regulation 118. In the test, it is monitored whether the specimen ignites, creates flaming droplets, and if these droplets ignite cotton wool placed under the specimen. For the material to pass the test, there must be no formation of flaming drops that ignite the cotton wool. Measurlabs can offer accredited test reports for the UN/ECE R118 Annex 7 test, as well as the Annex 6 and Annex 8 tests. Non-isotropic materials must be tested from both sides, which means that double the number of samples is required.

IMO 2010 FTP Code Part 8 testing for upholstered furniture is used to assess the suitability of materials for maritime use. The results can be used for type approval (wheel mark). The testing is performed on the actual product or a small-scale test chair consisting of the cover and filling components of the product. Materials needed for the test are as follows x 3: Cover: 800 mm x 650 mm, Back-filling: 450 mm x 300 mm x 75 mm , Seat-filling: 450 mm x 150 mm x 75 mm. During the cigarette test, a cigarette is lighted and positioned axially along the junction between the seat and the back. The test assembly is not allowed to smolder after one hour from the beginning of the test. In the burner tube test, a burner tube with a propane flame is allowed to burn for 20 seconds, positioned axially along the junction between the seat and the back. No flaming or progressive smoldering is allowed to continue for more than 120 seconds after the removal of the burner tube.

This metal screening analysis includes the semi-quantitative determination of 70 elements. The method can be used, for example, to determine the background concentrations of metals in environmental samples or to study the elemental distribution of unknown samples. Screening is also often performed to assess which metals should be analyzed by a quantitative method. The measurement is performed using a high-resolution ICP-MS technique (ICP-SFMS), which can identify very low elemental concentrations. A semi-quantitative determination of the following elements is included: Ag, Al, As, Au, B, Ba, Be, Bi, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Dy, Er, Eu, Fe, Ga, Gd, Ge, Hf, Hg, Ho, I, Ir, K, La, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Os, P, Pb, Pd, Pr, Pt, Rb, Re, Rh, Ru, S, Sb, Sc, Se, Si, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, Tm, U, V, W, Y, Yb, Zn and Zr. However, please note that some elements may not be determinable due to matrix interference. During this semi-quantitative analysis, the instrument is calibrated for about 30 elements and the rest of the analytes are quantified using sensitivity factors for calibrated elements with similar mass and first ionization potential considering isotope abundances. Quantitative analysis is also available at an additional price. During this analysis, all elements are calibrated (excluding halogens and Os). Please ask for an offer for this service.

The Herzberg staining test by the ISO 9184-3 standard is used to determine the main fiber content of paper and board. In the test, a saturated solution of zinc chloride, iodine, and potassium iodide is used to color the paper. The solution affects fibers differently and enables the qualitative and quantitative analysis of mechanical, rag, chemical, and semi-chemical pulps, regenerated cellulose fibers, and synthetic fibers in paper and board.

The chemical oxygen demand (COD) of pulp process liquid is measured according to the ISO 6060 standard to evaluate the environmental burden of the water sample. The sample must be kept at a temperature <5° C and analyzed within 5 days of sampling.

The molar mass distribution of biomass samples soluble in pure water or organic solvents (DMF, DMSO, and THF) is measured with gel permeation chromatography with a refractive index detector (GPC-RID). The system is calibrated with polystyrene and dextran standards. A Pullulan standard is also available upon request. In the case of lignin samples, molar mass distribution is analyzed using size exclusion chromatography (SEC) coupled with a UV detector at 256 nm wavelength. The lignin is dissolved in a suitable solvent before analysis. The SEC system is calibrated with a polystyrene sulfonate standard. A borate buffer is used to set the pH for the eluent.

Determination of the total organic fluorine (TOF) content in combustible materials by combustion ion chromatography (CIC). TOF analysis gives information about the total amount of organic fluorinated compounds. It can also be used to evaluate the presence of per- and polyfluoroalkyl substances (PFAS) in the material, even though individual PFAS compounds can't be analyzed with this method. The analysis is suitable for many different materials. Please describe the sample in detail when requesting an offer to help us prepare a quote quickly.