PFAS in packaging and packaging raw materials

Direct and oxidative TOP assay for quantification of target PFAS and precursor compounds in packaging materials, designed to verify compliance with the EU Packaging and Packaging Waste Regulation (PPWR). The service includes analysis of PFAS both with and without oxidation of the sample. The extraction is performed using alkaline MeOH under sonication in accordance with EN 17681-1:2025. This enables the measurement of both free PFAS and PFAS derived from precursors, released by the oxidation. Product parameter Description Total substances covered 82 Type of substances covered (non-exhaustive) Fluorotelomers (alcohols, acrylates, iodides, sulfonic acids, carboxylic acids, phosphates), perfluoroalkyl carboxylic acids (C3-C20), perfluoroalkyl sulfonic acids (C1-C13), PFOS and related compounds, PFOA and related compounds, PFHxS and related compounds, FOSE, FOSAA, FTCA, Gen X Suitable matrices Plastics, paper and board, metals, textiles, leather, laminates, molded fiber, wood Compliance assessment Article 5 of Packaging and Packaging Waste regulation: 25 ppb for individual targeted PFAS and , 250 ppb for the combined sum of targeted PFAS and precursors.

Analysis of PAH compounds in plastic, rubber, paper, board, and products made from these raw materials (e.g., textiles, toys, packaging materials) as required by the REACH Regulation (EC) No 1907/2006. Test package includes the following substances, restricted under Entry 50 of Annex XVII to the REACH Regulation: Benzo(a)pyrene [benzo(def)chrysene] [CAS: 50-32-8] , Benzo(e)pyrene [CAS: 192-97-2] , Benzo(a)anthracene [CAS: 56-55-3] , Chrysene [CAS: 218-01-9] , Benzo(b)fluoranthene [CAS: 205-99-2] , Benzo(j)fluoranthene [CAS: 205-82-3] , Benzo(k)fluoranthene [CAS: 207-08-9], Dibenzo(a,h)anthracene [CAS: 53-70-3].

Phthalates are a group of chemicals widely used as plasticizers, which make plastics more flexible and durable. They have also been used as additives in products such as cosmetics and personal care items. Several phthalates have been identified as endocrine-disrupting agents or as chemicals toxic to reproduction. Exposure to phthalates can occur through: Oral exposure Food: Exposure occurs via migration from food packaging., Children's toys: Children often put toys in their mouths.., Inhalation: Breathing in dust from vinyl flooring or fragrances (like perfumes) can cause exposure to phthalates via inhalation., Skin contact: Phthalates present in cosmetics, lotions, and soaps can be absorbed through the skin.. For other listed matrices apart from cosmetics, the analysis package covers the following substances included in the REACH Authorization List: Substance Abbreviation CAS number Diisobutyl phthalate DIBP 84-69-5 Dibutyl phthalate DBP 84-74-2 Benzyl butyl phthalate BBP 85-68-7 Bis(2-ethylhexyl) phthalate DEHP 117-81-7 Di(n-octyl) phthalate DNOP 117-84-0 Diisononyl phthalate DINP 68515-48-0 Diisodecyl phthalate DIDP 26761-40-0 Products that contain restricted phthalates in concentrations higher than 0.1% may be removed from the market. The analysis package for cosmetic products contains the following phthalates: Substance Abbreviation CAS number Bis(2-ethylhexyl) phthalate DEHP 117-81-7 Benzyl butyl phthalate BBP 85-68-7 Dibutyl phthalate DBP 84-74-2 Diisononyl phthalate DINP 68515-48-0 Di(n-octyl) phthalate DNOP 117-84-0 Diisodecyl phthalate DIDP 26761-40-0 All the above-mentioned substances are prohibited in cosmetic products (Annex II of Regulation (EC) No 1223/2009).

Analysis for quantifying dioxins and furans (PCDD/F) in various packaging materials (e.g. food and cosmetics packaging) and their raw materials, including plastics, paper, and rubber. Dioxins and furans are a family of chlorine-containing chemicals considered bioaccumulating, persistent organic pollutants (POPs) that can be toxic even at low doses. While regulatory limits apply mainly to food and feed, packaging materials can be a source of indirect exposure to dioxins and furans. Recycled materials tend to pose relatively high risks, depending on the quality of the raw material and the effectiveness of the decontamination process. The following substances are included in the analysis: Dibenzo-p-dioxins (PCDDs) Polychlorinated dibenzofurans (PCDFs) 2,3,7,8-TCDD. 2,3,7,8-TCDF. 1,2,3,7,8-PeCDD. 1,2,3,7,8-PeCDF. 1,2,3,4,7,8-HxCDD. 2,3,4,7,8-PeCDF. 1,2,3,6,7,8-HxCDD. 1,2,3,4,7,8-HxCDF. 1,2,3,7,8,9-HxCDD. 1,2,3,6,7,8-HxCDF. 1,2,3,4,6,7,8-HpCDD. 1,2,3,7,8,9-HxCDF. OCDD. 2,3,4,6,7,8-HxCDF. 1,2,3,4,6,7,8-HpCDF. 1,2,3,4,7,8,9-HpCDF. OCDF. Testing is often performed for the following reasons: Analyzing recycled PE, PP, and LDPE intended for cosmetics packaging according to CosPaTox guidelines., Analyzing paper and board bleached with elementary chlorine according to the requirements of TemaNord 2008:515 guidelines..

Determination of the total organic fluorine (TOF) content in combustible materials using combustion ion chromatography (CIC). By default, TOF is analyzed as total fluorine (TF). If required, total inorganic fluorine (TIF) can be measured as well, and TOF calculated as the difference between TF and TIF. TOF analysis gives information about the total amount of organic fluorinated compounds. It can also be used to evaluate the presence of per- and polyfluoroalkyl substances (PFAS) in the material, even though individual PFAS compounds can't be analyzed with this method. The analysis is suitable for many different materials. Please describe the sample in detail when requesting an offer to help us prepare a quote quickly.

We offer two extended analysis packages for phthalates and plasticizers in various matrices using the GC-MS technique. The first package covers 22 compounds with reporting limits significantly lower than the industry standard of 0.001%: Substance name Abbreviation CAS No Reporting limit (LOD) (wt%) Dimethyl phthalate DMP 131-11-3 0.00005 Diethyl phthalate DEP 84-66-2 0.00005 Triethyl citrate TEC 77-93-0 0.00025 Diallyl phthalate DAP 131-17-9 0.00005 Dipropyl phthalate DPrP 131-16-8 0.00005 Diisobutyl phthalate DIBP 84-69-5 0.00005 Dibutyl phthalate DBP 84-74-2 0.00005 Di-n-pentyl phthalate DPP 131-18-0 0.00005 Di-n-hexyl phthalate DHXP 84-75-3 0.00005 Dibutyl sebacate DBS 109-43-3 0.00005 Acetyl tributyl citrate ATBC 77-90-7 0.00005 Benzyl butyl phthalate BBP 85-68-7 0.00005 Diethylhexyl adipate DEHA 103-23-1 0.00005 Dicyclohexyl phthalate DCHP 84-61-7 0.00005 Di-2-ethylhexyl phthalate DEHP 117-81-7 0.00005 Di-n-octyl phthalate DNOP 117-84-0 0.00005 DINCH DINCH 166412-78-8 0.00005 Di-2-ethylhexyl sebacate - 122-62-3 0.00005 Dioctyl terephthalate DOTP 6422-86-2 0.00005 Diisononyl phthalate DINP 28553-12-0 0.00025 Diisodecyl phthalate DIDP 26761-40-0 0.00025 Phthalic anhydride - 85-44-9 0.00005 The other package covers 43 compounds with a detection limit of 0.001%. The full list of target substances is available upon request. Please let us know which option you are interested in when requesting a quote.

Cyclosiloxanes are the primary building blocks of siloxane polymers and ultimately silicone rubber. Hence, cyclosiloxanes can remain in the final silicone article as residual impurities. Several cyclosiloxanes (D4, D5, D6) are considered harmful to the environment and human health. These three substances are listed in the REACH Candidate List of substances of very high concern (SVHC). The analysis package covers the following substances Substance CAS N:o Abbreviation Hexamethylcyclotrisiloxane 541-05-9 D3 Octamethylcyclotetrasiloxane 556-67-2 D4 Decamethylcyclopentasiloxane 541-02-6 D5 Dodecamethylcyclohexasiloxane 540-97-6 D6 Tetradecamethylcycloheptasiloxane 107-50-6 D7 Hexadecamethylcyclooctasiloxane 556-68-3 D8 The Nordic Swan Ecolabel criteria for greaseproof paper sets the limit values for D4, D5, and D6 impurities in silicone coating as 400 ppm per substance and 1000 ppm for the sum of D4, D5, and D6.

Determination of isothiazolinones in food contact materials and consumer goods. Isothiazolinones are common preservatives (biocides) in cosmetics, chemical formulations, and printing inks. Isothiazolinone content is restricted under several EU directives and regulations, including the Toy Safety Directive 2009/48/EC, the Cosmetic Products Regulation (EC) No 1223/2009, and the Food Contact Plastics Regulation (EU) No 10/2011. For paper and board intended for food contact, limits are specified in German BfR recommendation XXXVI. For testing compliance with BfR recommendation XXXVI, we can offer the following packages for analysis from aqueous extracts (EN 645 / EN 647): Substance Abbreviation CAS Basic package Extended package 1,2-benzisothiazolin-3(2H)-one BIT 2634-33-5 x x 2-methyl-2H-isothiazol-3-one MIT 2682-20-4 x x 5-chloro-2-methyl-2H-isothiazol-3-one CMIT 26172-55-4 x x CMIT/MIT 3:1 mixture - 55965-84-9 x x 2-octyl-2H-isothiazole-3-one OIT 26530-20-1 x 2-mercaptobenzothiazole (MBT) MBT 149-30-4 x 4,5-dichloro-2-octyl-2H-isothiazol-3-one DCOIT 64359-81-5 x 2-methyl-1,2-benzothiazol-3(2H)-one MBIT 2527-66-4 x For paper and board with grammage exceeding 450 gsm, the extended package with the lower reporting limit will be used automatically.

The EU Packaging and Packaging Waste Regulation (PPWR) limits heavy metal content in all packaging and PFAS content in food packaging. This analysis package includes the following analyses to demonstrate compliance: Total fluorine (TF), Heavy metals (Pb, Cd, Hg, and Cr), Further total organic fluorine (TOF) and targeted PFAS analyses where required/requested.. The displayed typical price applies to TF analysis and heavy metal determination, which are sufficient for most materials. According to a recently published Commission guidance document, further PFAS testing is not required if TF content is less than 50 ppm. If the 50 ppm limit is exceeded, the Commission recommends the following steps: TOF analysis with py-GC/MS to determine whether the fluorine is organic (potentially PFAS) or inorganic (e.g., fluorine impurities in talc and other mineral fillers). If TOF content is less than 50 ppm, no further testing is needed., If the TF and TOF analyses are not sufficient to show that PFAS are not present, a direct TOP assay (total oxidizable precursors) should be used to check compliance with the limits set for individual PFAS compounds and the sum of PFAS.. Both of these analyses are also available at Measurlabs. Please describe the composition of the packaging material when requesting an offer (materials with metal components may require the testing procedure to be modified). Please also let us know how many materials you need tested, as we are happy to offer discounted pricing for large batches.

Determination of mineral oil saturated hydrocarbons (MOSH) with polyolefin oligomeric saturated hydrocarbons (POSH) and mineral oil aromatic hydrocarbons (MOAH) in various matrices, including: Food contact materials (e.g., paper, board, plastics, rubber), Printing inks (incl. carbon black), Cosmetic products and raw materials, Lubricating oils and greases, white oils. The results are reported as the concentrations of fractions of MOSH/POSH and MOAH, with grouping based on the number of carbon atoms in the substances. The reported fractions are listed in the table below: MOSH/POSH (C10-C50), total MOAH (C10-C50), total MOSH/POSH (≥C10-≤C16) MOAH (≥C10-≤C16) MOSH/POSH (>C16-≤C20) MOAH (>C16-≤C25) MOSH/POSH (>C20-≤C25) MOAH (>C25-≤C35) MOSH/POSH (>C25-≤C35) MOAH (>C35-≤C50) MOSH/POSH (>C35-≤C40) MOSH/POSH (>C40-≤C50) In case the sample contains high amounts of MOSH, POSH, or poly alpha olefins (PAO), the levels should be indicated before shipping samples. Moreover, the LOQ is higher for samples with high MOSH, POSH, or PAO content due to dilution. Additionally, the safety data sheets (SDS) should be supplied with the samples when available.