Nitrogen content according to ASTM D5762

Diesel exhaust fluid (DEF) is an additive used in diesel-powered vehicles to help the catalytic reduction of nitrous oxides. Thus, the use of AdBlue and other exhaustive fluids improves ambient air quality. DEF testing package according to ISO 22241:2019 includes the measurements listed below: Urea content (ISO 22241-2C), Density at 20 °C (EN ISO 12185) , Refractive index at 20 °C (ISO 22241-2C), Alkalinity as NH₃ (ISO 22241-2D), Biuret (ISO 22241-2E), Aldehydes (ISO 22241-2F), Insoluble matter (ISO 22241-2G), Phosphate (ISO 22241-2H), Determination of Al, Ca, Cr, Cu, Fe, K, Mg, Na, Ni, and Zn content (ISO 22241-2I).

This metal screening analysis includes the semi-quantitative determination of 70 elements. The method can be used, for example, to determine the background concentrations of metals in environmental samples or to study the elemental distribution of unknown samples. Screening is also often performed to assess which metals should be analyzed by a quantitative method. The measurement is performed using a high-resolution ICP-MS technique (ICP-SFMS), which can identify very low elemental concentrations. A semi-quantitative determination of the following elements is included: Ag, Al, As, Au, B, Ba, Be, Bi, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Dy, Er, Eu, Fe, Ga, Gd, Ge, Hf, Hg, Ho, I, Ir, K, La, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Os, P, Pb, Pd, Pr, Pt, Rb, Re, Rh, Ru, S, Sb, Sc, Se, Si, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, Tm, U, V, W, Y, Yb, Zn and Zr. However, please note that some elements may not be determinable due to matrix interference. During this semi-quantitative analysis, the instrument is calibrated for about 30 elements. The rest of the analytes are quantified using sensitivity factors for calibrated elements with similar mass and first ionization potential, considering isotope abundances. Quantitative analysis is also available at an additional price. During this analysis, all elements are calibrated (excluding halogens and Os). Please ask for an offer for this service.

Determination of the total organic fluorine (TOF) content in combustible materials using combustion ion chromatography (CIC). By default, TOF is analyzed as total fluorine (TF). If required, total inorganic fluorine (TIF) can be measured as well, and TOF calculated as the difference between TF and TIF. TOF analysis gives information about the total amount of organic fluorinated compounds. It can also be used to evaluate the presence of per- and polyfluoroalkyl substances (PFAS) in the material, even though individual PFAS compounds can't be analyzed with this method. The analysis is suitable for many different materials. Please describe the sample in detail when requesting an offer to help us prepare a quote quickly.

Determination of carbon, hydrogen, nitrogen, sulfur, and oxygen content of an organic sample. CHNS analysis (”LECO analysis”) is performed using a flash combustion method, where the sample is combusted under 25 kPa of O2 at an elevated temperature (1,000 °C), followed by gas chromatography separation and detection using a thermal conductivity detector. Oxygen is analyzed by reduction on granulated carbon at 1480 °C, utilizing high-temperature thermal decomposition and conversion of oxygen into carbon monoxide before gas chromatography separation and detection with a thermal conductivity detector. The sample can be either solid or liquid, but water in the sample affects the results. In the case of aqueous samples, it is possible to dry the sample before analysis. The displayed price includes the full CHNOS package with two parallel measurements and applies to conventional organic samples. The results are reported as wt-% of the initial sample. The addition of ash, drying, and dry loss measurements will increase the minimum required sample material to 300 mg. The analysis gives the total carbon, hydrogen, nitrogen, sulfur, and oxygen content of the material, but it does not identify any chemical structures. The measurement can be combined with other methods, such as GC-MS, 1H, and 13C NMR, to perform substance structure identification. Analysis can be split into the following packages: CHN, O, and S.

Determination of total halogen content (F, Cl, Br) in aromatic hydrocarbon matrices such as pyrolysis oil and other petroleum products, where halogen impurities can affect catalyst performance, corrosion risk, and downstream processing. Testing is conducted according to EN 15408, or DIN 51727, with the most suitable method selected based on the sample matrix and expected concentration levels. All methods are based on oxygen combustion followed by detection using ion chromatography or other suitable analytical techniques. The typical reporting range is between 10 and 2000 mg/kg per element. The displayed price applies to small sample sets. Please specify the number of samples when requesting a quote, as volume discounts are available for larger batches.

Our δ13C stable isotope analysis determines the ratio of 13C to 12C in a given sample material by a continuous flow isotope ratio mass spectrometer (IRMS). Results are expressed in per mille (‰) as the deviation of the isotope ratio from a standard reference material. We have more than 30 IAEA, USGS, and in-house isotopic standards available to accommodate a wide range of expected ratios. The price and turnaround time displayed apply to conventional sample matrices. The analysis is suitable for a wide range of sample materials, including, but not limited to, those listed in the table below. All of our stable isotope analyses are conducted at ISO 17025-accredited facilities. Please contact us using the form below to arrange testing on your samples.

Quantification of total sulfur in liquid fuels and oils in accordance with ASTM D5453 or ASTM D2622. The method is selected based on the expected sulfur level: ASTM D5453 is applied to samples with low to moderate sulfur levels and has a limit of quantification of 0.5 mg/kg., ASTM D2622 is used for samples with higher sulfur concentrations and has a limit of quantification of 3 mg/kg.. Samples must be liquid, homogeneous and particle-free, or easily filterable. Results are reported in mg/kg or mg/l. Sulfur testing is commonly performed to verify conformity with environmental fuel specifications, such as the 10 mg/kg limit for petrol and diesel under Directive 2009/30/EC. Please note that the displayed price applies to small sample sets; larger batches and recurring orders are generally eligible for volume discounts.

Determination of elemental impurities in pyrolysis oil by microwave digestion (in-house method) followed by ICP-OES analysis according to EN ISO 11885.  The following elements are quantified after microwave digestion: Al, Ag, As, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Sb, Se, Sr, Ti, Tl, V, Zn, S, Si, and P. Results are reported in mg/kg. The displayed price applies to small sample sets; larger batches and recurring orders are eligible for volume discounts.

Volumetric (static) or dynamic (pulse) chemisorption analysis by CO or H2. The method is mainly used to determine catalyst activity and active sites. When coupled with TPX (temperature programmed experiments, TPO, TPR, TPD), this method can give information about adsorbed species and surface species. Chemisorption can also be conducted with other reactive gases, please contact us for more information.

Spark-OES is a commonly used method to determine the elemental composition of metals and alloys. The method provides a better alternative to other similar analysis techniques (ICP-OES, ICP-MS, XRF) due to its speed and low detection limits. All metallic elements and some non-metallic elements, such as C, N, and S, can be detected in the ppm range. The method is suitable for solid metal pieces with a minimum size of 1 x 1 cm. Sample preparation is included in the analysis.