BTEX in natural- and biogas with GC-MS

Analysis of gaseous samples using Raman spectroscopy.

Determination of selected volatile organic compounds (VOC) in water using the GC-MS and GC-FID techniques. Analysis can be conducted according to the following standard methods: EPA 624, EPA 5021A, EPA 8260, EPA 8015, EN ISO 10301, ISO 11423-1, and EN ISO 15680 The results of the analysis are reported in µg/L. Analysis includes the following analytes: Analyte: Reporting limits: chloromethane 1 µg/l bromomethane 1 µg/l dichloromethane 0.1 µg/l dibromimetaani 1 µg/l bromochloromethane 2 µg/l trichloromethane (chloroform) 0.1 µg/l tribromomethane (bromoform) 0.2 µg/l bromodichloromethane 0.1 µg/l dibromochloromethane 0.1 µg/l sum 4 trihalometanit 0.5 µg/l tetrachloromethane 0.1 µg/l trichlorofluoromethane 1 µg/l dichlorodifluoromethane 1 µg/l monochloroethane 1 µg/l 1,1-dichloroethane 0.1 µg/l 1,2-dichloroethane 0.1 µg/l 1,2-dibromietaani 0.5 µg/l 1,1,1-trichloroethane 0.1 µg/l 1,1,2-trichloroethane 0.1 µg/l 1,1,1,2-tetrachloroethane 0.1 µg/l 1,1,2,2-tetrachloroethane 1 µg/l vinyl chloride 0.1 µg/l 1,1-dichloroethene 0.1 µg/l cis-1,2-dichloroethene 0.1 µg/l trans-1,2-dichloroethene 0.1 µg/l amount of 1,2-dichloroethene 0.2 µg/l trichloroethylene 0.1 µg/l sum of 11 chlorinated hydrocarbons 1.1 µg/l tetrachloroethene 0.1 µg/l Sum of trichloroethylene and tetrachloroethylene 0.2 µg/l sum 5 chlorinated ethylenes 0.5 µg/l 1,2-dichloropropane 1 µg/l 1,3-dichloropropane 1 µg/l 2,2-dichloropropane 1 µg/l 1,2,3-trichloropropane 1 µg/l 1,2-dibromo-3-chloropropane 1 µg/l 1,1-dichloro-1-propene 1 µg/l cis-1,3-dichloro-1-propene 1 µg/l trans-1,3-dichloropropene 1 µg/l hexachlorobutadiene 1 µg/l 2-chlorotoluene 1 µg/l 4-chlorotoluene 1 µg/l monochlorobenzene 0.1 µg/l bromobenzene 1 µg/l 1,2-dichlorobenzene 0.1 µg/l 1,3-dichlorobenzene 0.1 µg/l 1,4-dichlorobenzene 0.1 µg/l amount of 3 dichlorobenzene 0.3 µg/l 1,2,3-trichlorobenzene 0.1 µg/l 1,2,4- trichlorobenzene 0.1 µg/l 1,3,5-trichlorobenzene 0.1 µg/l amount of 3 trichlorobenzene 0.4 µg/l benzene 0.1 µg/l toluene 0.5 µg/l ethylbenzene 0.1 µg/l o-xylene 0.1 µg/l m/p-xylene 0.2 µg/l sum of xylenes 0.3 µg/l sum of BTEX 1 µg/l styrene 0.2 µg/l isopropylbenzene 1 µg/l n-propylbenzene 1 µg/l 1,2,4-trimethylbenzene 1 µg/l 1,3,5-trimethylbenzene 1 µg/l n-butylbenzene 1 µg/l sec-butylbenzene 1 µg/l tert-butylbenzene 1 µg/l p-isopropyltoluene 1 µg/l naphthalene 1 µg/l Diisopropyl ether (DIPE) 0.6 µg/l ETBE (ethyl tert-butyl ether) 0.2 µg/l MTBE (methyl tert-butyl ether) 0.2 µg/l tert-amyl ethyl ether (TAEE) 0.2 µg/l TAME 0.2 µg/l tert-butyl alcohol (TBA) 5 µg/l ethanol 100 µg/l A customized offer can also be prepared if you are interested in analyzing only individual compounds from a sample. Suitable sample containers for analysis can be ordered through us. Sample containers picked up from Measurlabs are included in the price of the analysis, but sample containers can also be shipped to the customer for a separate fee.

Our δ13C stable isotope analysis determines the ratio of 13C to 12C in a given sample material by a continuous flow isotope ratio mass spectrometer (IRMS). Results are expressed in per mille (‰) as the deviation of the isotope ratio from a standard reference material. We have more than 30 IAEA, USGS, and in-house isotopic standards available to accommodate a wide range of expected ratios. The price and turnaround time displayed apply to conventional sample matrices. The analysis is suitable for a wide range of sample materials, including, but not limited to, those listed in the table below. All of our stable isotope analyses are conducted at ISO 17025-accredited facilities. Please contact us using the form below to arrange testing on your samples.

Determination of aliphatic alkane concentrations in natural gas and biogas by in-house µGC-µTCD analysis. The following compounds are quantified: Methane (CH4), Ethane (C2H6), Propane (C3H8), Isobutane (C4H10), Butane (C4H10), Isopentane and pentane (C5H12), Hexane (C6H14). The LOQ is 10 ppm-vol for all target compounds. Results are reported in V-%. Please note that the safety data sheet (SDS) must be provided with gas samples. The samples should also be shipped to Measurlabs soon after sampling, as some analytes may escape the sampling vessel over time.

The EN 16516 standard outlines a test chamber method for determining volatile and semi-volatile organic compound (VOC and SVOC) emissions from construction products. Emissions are typically measured 28 days after the installation of representative test specimens in the test chamber. Conditions within the chamber are kept constant throughout the testing period, with the temperature at 23 ± 1 °C, relative humidity at 50 ± 5 %, air change rate at 0.5 per hour, and air velocity above the specimen at 0.1–0.3 m/s. The loading factor (ratio of exposed test specimen area to the empty chamber volume) is chosen based on product type and intended conditions of use. At the end of the test period, air is collected from the chamber using adsorbent tubes and analyzed by thermal desorption GC-MS (TD-GC/MS) to identify and quantify target compounds. The results will include: Individual concentrations of identified target compounds (including known carcinogenic VOCs), identified non-target compounds, and unidentified compounds. The last two are reported as toluene equivalents., Total VOC (TVOC), calculated as the sum of all compounds (identified and unidentified) eluting between and including n-hexane and n-hexadecane., Total SVOC (TSVOC), calculated as the sum of all compounds eluting after n-hexadecane, up to and including n-docosane.. For compliance assessment, the measured VOC levels can be compared with limits specified in national emissions standards or sustainability certifications, such as the German AgBB, French ANSES, Finnish M1 Emission Classification, or the Nordic Swan Ecolabel. Depending on the scheme, maximum limits can apply to TVOC, total carcinogenic VOC, and/or individual compounds, such as formaldehyde. The results for individual compounds can also be compared with EU-LCI values, harmonized health-based reference values based on the ‘lowest concentration of interest’ concept.

Quantification of heating value, CH4, CO2, O2, N2, H2, and C2–C5 alkanes in natural gas and biogas samples with gas chromatography. The sample can be shipped in a gas bag or preferably in an adsorbent tube. Standard methods available: ASTM D1945, ASTM D1946, ASTM D3588. Ask our experts about the suitability of other sample vessels when requesting an offer.

Compositional analysis of gas samples in accordance with NF X 20-303, DIN 51872-4, or in-house µGC/µTCD methods. The most suitable method is selected based on the analyzed gas and target analyte(s). Any 1-8 analytes from the table below can be selected. The price will be determined based on the number of substances analyzed. Compound Formula LOQ (ppm-vol.) acetylene C2​H2 10 argon Ar 10 nitrogen N2 10 butane C4​H10 10 carbon dioxide CO2 10 sulfur dioxide SO2 20 water vapor H2​O 10 ethane C2​H6 10 ethylene C2​H4 10 helium He 10 hydrogen H2 5 hydrogen sulfide H2​S 10 isobutane C4​H10​ 10 isopentane C5​H12​ 10 methane CH4​ 10 carbon monoxide CO 10 oxygen O2​ 10 pentane C5​H12​ 10 propane C3​H8​ 10 nitrous oxide N2​O 10 Gas samples must be collected in 2L multifoil bags, and the safety data sheet (SDS) must be provided with the shipment. Quick delivery to Measurlabs after sampling is recommended, as some analytes may escape the sampling vessel over time. This is particularly relevant for H2, CO, CO2, and O2. When requesting a quote, please describe the sample matrix and list the target analytes.

Determination of the hydrogen sulfide (H₂S) content of natural gas or biogas samples. The analysis is conducted with µGC-µTCD equipment. Please contact Measurlabs experts to check the suitability of other sample vessels for the analysis.

Quantification of CH₄ (methane), CO₂ (carbon dioxide), O₂ (oxygen), N₂ (nitrogen), H₂ (hydrogen), H₂O (water), and C2-C5 alkanes in natural gas and biogas samples with gas chromatography. Please contact Measurlabs experts to check the sample vessel's suitability for the analysis.

Spark-OES is a commonly used method to determine the elemental composition of metals and alloys. The method provides a better alternative to other similar analysis techniques (ICP-OES, ICP-MS, XRF) due to its speed and low detection limits. All metallic elements and some non-metallic elements, such as C, N, and S, can be detected in the ppm range. The method is suitable for solid metal pieces with a minimum size of 1 x 1 cm. Sample preparation is included in the analysis.