Free isocyanate content in polyurethanes
Isocyanates are used as monomers in adhesives and polyurethane plastics or foams. Isocyanates that have been approved for use in food contact materials belong to Restriction Group (17) in Commission Regulation (EU) No 10/2011. These substances have a group restriction for both specific migration (not detected; 0.01 mg/kg of food) and residual content (1 mg/kg, expressed as isocyanate (NCO) moiety).
Depending on your needs, Measurlabs provides two analysis packages for determining residual isocyanate content:
Basic package
Compound | Abbreviation | CAS N:o |
|---|---|---|
2,4-toluene diisocyanate | 2,4-TDI | 584-84-9 |
2,6-toluene diisocyanate | 2,6-TDI | 91-08-7 |
toluene diisocyanates | TDI | 26471-62-5 |
diphenylmethane-4,4′-diisocyanate | 4,4'-MDI | 101-68-8 |
HDI | 822-06-0 |
Extended package
Compound | Abbreviation | CAS N:o |
|---|---|---|
2,4-toluene diisocyanate | 2,4-TDI | 584-84-9 |
2,6-toluene diisocyanate | 2,6-TDI | 91-08-7 |
toluene diisocyanates | TDI | 26471-62-5 |
3,3′-dimethyl-4,4′-diisocyanatobiphenyl | TODI | 91-97-4 |
diphenylmethane-2,4′-diisocyanate | 2,4'-MDI | 5873-54-1 |
diphenylmethane-2,2′-diisocyanate | 2,2'-MDI | 2536-05-2 |
diphenylmethane-4,4′-diisocyanate | 4,4'-MDI | 101-68-8 |
diphenylmethane diisocyanates | MDI | 26447-40-5 |
octadecyl isocyanate | ODI | 112-96-9 |
hexamethylene diisocyanate | HDI | 822-06-0 |
cyclohexyl isocyanate | CHI | 3173-53-3 |
1,5-naphthalene diisocyanate | NDI | 3173-72-6 |
1-isocyanato-3-isocyanatomethyl-3,5,5-trimethylcyclohexane | IPDI | 4098-71-9 |
dicyclohexylmethane-4,4′-diisocyanate | HMDI | 5124-30-1 |
phenyl isocyanate | PI | 103-71-9 |
m-xylylene diisocyanate | XDI | 3634-83-1 |
poly(isophorone diisocyanate) | poly-IPDI | 53880-05-0 |
Due to the low detection limit, this method also functions as a substitute for the specific migration test (assuming 100% migration) if the article or material is not exceptionally thick (> 30 g/dm2).
Aromatic isocyanates react with water, forming (potentially) carcinogenic primary aromatic amines that are covered by a separate test.
- Suitable sample matrices
- Plastics, elastomers, consumer goods, paper
- Required sample quantity
- 20 g
- Typical turnaround time
- 4 weeks after receiving the samples
- Detection limit
- At least 0.05 mg/kg
- Available quality systems
- Accredited testing laboratory
- Device types
- Standard
- Method expert
Price
We also charge a 97 € service fee per order.
Large batches of samples are eligible for discounts.
Questions? We're happy to help.
Questions? We're happy to help.
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