Chlorophenols in aqueous extracts of paper and board

Determination of bisphenol S (CAS 80-09-1) content in various matrices with LC-MS, including: Consumer goods made from plastic, elastomers, and rubber, Food packaging (plastic, paper, multi-materials). Testing is recommended especially for paper and board food packaging that contains recycled fibers and comes into contact with moist and fatty foods. To be compliant with German BfR Recommendation XXXVI, such packaging must not release bisphenol S into food in amounts exceeding 0.05 mg/kg. Extraction is possible with various techniques, including: Extraction method Intended purpose Standard (extraction) Suitable matrices Reporting limit Acetonitrile extraction Test for residual content of BPS In-house Plastic, rubber 0.003 mg/kg of sample Methanol extraction under sonication Test for residual content of BPS In-house Paper, board 0.01 mg/l of extract Cold water extraction Simulate migration into aqueous foods for non-coated paper EN 645 Paper, board 0.01 mg/l of extract Hot water extraction Simulate migration into aqueous foods for non-coated paper for baking purposes EN 647 Paper, board 0.01 mg/l of extract Solvent extraction Simulate migration into fatty foods for non-coated paper EN 15519 Paper, board 0.01 mg/l of extract

As there is no harmonized EU regulation for using wood in food contact applications, compliance should be assessed based on other resources, such as the national legislation of member states. This test package is based on the requirements of French Information note n°2012-93 (Note d'information n° 2012-93) for coated and non-coated wood intended for food contact. The following analyses are included in the displayed price: Test parameter Test method/standard Method of extraction or preparation Transfer of odor and flavor into food DIN 10955 Water extract or contact with model food Heavy metals in water extract (Pb, Cd, Hg) ICP-MS Cold or hot water extract (EN 645 / EN 647) Formaldehyde in water extract EN 1541 Cold or hot water extract (EN 645 / EN 647) Polychlorinated biphenyls (PCB28, PCB52, PCB101, PCB118, PCB153, PCB180) GC-MS In-house method Pentachlorophenol (PCP) content GC-MS CEN/TR 14823 In addition to the tests listed above, a pesticide screening should be performed for wood treated with antifungal substances (so-called "anti-blue" protection). The analysis covers 715 substances and is available for an additional cost of 298 EUR. In most cases, this test package is sufficient to establish food contact compliance of non-coated wood or articles thereof. If the wood has been coated with a lacquer or varnish, has been painted, or contains adhesives, complementary testing could be required (e.g., migration of primary aromatic amines, migration of mineral oil (MOSH/POSH and MOAH hydrocarbons). Our experts are happy to support you by reviewing the documentation of the coating material and/or the adhesive to determine the full scope of required testing.

Glutaraldehyde is a slimicide used to control microbial growth in paper and paperboard packaging. Its use in food packaging is allowed according to BfR XXXVI, however, no more than 2 mg of glutaraldehyde must be detectable in 1 kg of the finished product.

Acrylamide (CAS: 79-06-1) is used in certain sizing and retention agents in the production of fiber-based food packaging. It is classified as a potential human carcinogen, and its migration into food is restricted under several EU and national regulations. A migration limit of 0.01 mg/kg was recently introduced for acrylamide release from paper- and board-based food contact materials by the latest version of German BfR recommendation XXXVI (October 2025). The same limit also applies to migration from plastic food contact materials under Regulation (EU) No 10/2011. Specific migration from plastics or rubber can be determined using several food simulants. Paper and board, for which conventional migration testing is not suitable, are analyzed using aqueous or solvent extractions (EN 645, EN 647, EN 15519).

Epichlorohydrin is a highly reactive electrophilic compound used to produce glycerol, plastics, epoxy glues and resins, epoxy diluents, and elastomers. The compound is included under 'Sizing agents' in the positive list of the BfR XXXVI recommendation on paper and board food contact materials. The hydrolysis products of epichlorohydrin are controlled as follows: 1,3-Dichloro-2-propanol [1,3-DCP, CAS 96-23-1] must not be detectable in the water extract of the finished product (detection limit 2 µg/l). , The transfer of 3-monochloro-1,2-propanediol [3-MCPD CAS 96-24-2] into the water extract of the finished products must be as low as technically achievable, and a limit of 12 µg/l must not be exceeded in any case..

Determination of isothiazolinones in consumer goods. Isothiazolinones are common preservatives (biocides) in cosmetics, chemical formulations, and printing inks. The following isothiazolinones are included in the analysis: 1,2-benzisothiazolin-3(2h)-one (BIT, CAS: 2634-33-5), 2-methyl-2H-isothiazol-3-one (MIT, CAS: 2682-20-4), 5-chloro-2-methyl-2H-isothiazol-3-one (CMIT, CAS: 26172-55-4), CMIT/MIT mixture (CAS: 55965-84-9). Maximum content limits for isothiazolinones are specified in several EU directives and regulations, including the Toy Safety Directive 2009/48/EC, the Cosmetic Products Regulation (EC) No 1223/2009, and the Food Contact Plastics Regulation (EU) No 10/2011.

Analysis for quantifying dioxins and furans (PCDD/F) in various packaging materials (e.g. food and cosmetics packaging) and their raw materials, including plastics, paper, and rubber. Dioxins and furans are a family of chlorine-containing chemicals considered bioaccumulating, persistent organic pollutants (POPs) that can be toxic even at low doses. While regulatory limits apply mainly to food and feed, packaging materials can be a source of indirect exposure to dioxins and furans. Recycled materials tend to pose relatively high risks, depending on the quality of the raw material and the effectiveness of the decontamination process. The following substances are included in the analysis: Dibenzo-p-dioxins (PCDDs) Polychlorinated dibenzofurans (PCDFs) 2,3,7,8-TCDD. 2,3,7,8-TCDF. 1,2,3,7,8-PeCDD. 1,2,3,7,8-PeCDF. 1,2,3,4,7,8-HxCDD. 2,3,4,7,8-PeCDF. 1,2,3,6,7,8-HxCDD. 1,2,3,4,7,8-HxCDF. 1,2,3,7,8,9-HxCDD. 1,2,3,6,7,8-HxCDF. 1,2,3,4,6,7,8-HpCDD. 1,2,3,7,8,9-HxCDF. OCDD. 2,3,4,6,7,8-HxCDF. 1,2,3,4,6,7,8-HpCDF. 1,2,3,4,7,8,9-HpCDF. OCDF. Testing is often performed for the following reasons: Analyzing recycled PE, PP, and LDPE intended for cosmetics packaging according to CosPaTox guidelines., Analyzing paper and board bleached with elementary chlorine according to the requirements of TemaNord 2008:515 guidelines..

Determination of the total organic fluorine (TOF) content in combustible materials using combustion ion chromatography (CIC). By default, TOF is analyzed as total fluorine (TF). If required, total inorganic fluorine (TIF) can be measured as well, and TOF calculated as the difference between TF and TIF. TOF analysis gives information about the total amount of organic fluorinated compounds. It can also be used to evaluate the presence of per- and polyfluoroalkyl substances (PFAS) in the material, even though individual PFAS compounds can't be analyzed with this method. The analysis is suitable for many different materials. Please describe the sample in detail when requesting an offer to help us prepare a quote quickly.

Screening of volatile organic compounds (VOC) from paper, board, and plastics. The method can be used to analyze volatile residues from printed packaging. For evaluation of recycling process efficiency, please see our extended package for VOC screening. The following substances are included in this analysis package: Substance CAS No Methyl propylene glycol (1-methoxy-2-propanol) 107-98-2 Buthyl glycol (2-Butoxy ethanol) 111-76-2 Ethyl glycol (2-Ethoxyethanol) 110-80-5 Ethyl glycol acetate (2-Ethoxyethyl acetate) 111-15-9 Methyl glycol (2-Methoxyethanol) 109-86-4 Methyl glycol acetate (2-Methoxyethanol acetate) 110-49-6 3-Ethoxy-1-propanol 111-35-3 Acetyl acetone 123-54-6 Acetone 67-64-1 Ethanol 64-17-5 Isobutanol 201-148-0 2-propanol, Isopropanol (IPA) 67-63-0 Methanol 67-56-1 1-Butanol 71-36-3 1-Propanol 71-23-8 Benzene 71-43-2 Cyclohexane 110-82-7 Ethylbenzene 100-41-4 Ethyl acetate 141-78-6 Isobutyl acetate 110-19-0 Isopropyl acetate 108-21-4 Isooctane 540-84-1 2-butanone, methyl ethyl ketone (MEK) 78-93-3 Methyl isobutyl ketone (MIBK) 108-10-1 Methyl acetate 79-20-9 Toluene 108-88-3 Trichloroethylene 79-01-6 Xylene 1330-20-7 n-Butyl Acetate 123-86-4 n-Heptane 142-82-5 n-Hexane 110-54-3 n-Octane 111-65-9 n-Propyl acetate 109-60-4

Alkyl ketene dimers (AKD) are used as hydrophobic sizing agents in paper and board to improve water resistance. However, AKDs not bound by the fiber matrix can hydrolyse into dialkyl ketones (DAKs). For paper and board intended for food contact, BfR recommendation XXXVI states that DAK transfer into foodstuff may not exceed 5 mg/kg food. The package includes an analysis of the following substances from a food simulant: Substance Structure CAS No 16-Hentriacontanone (palmitone) C31H62O 502-73-8 16-Tritriacontanone C33H66O 15740-35-9 18-Pentatriacontanone (stearone) C35H70O 504-53-0 The analysis can be performed with the following simulants and approaches: Food simulant Type of testing Applicable standard Iso-octane Conventional migration EN 13130-1 Iso-octane Solvent extraction EN 15519 Tenax Conventional migration EN 14338